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The Chernobyl Power Complex, lying about 130 km north of Kiev, Ukraine, and about 20 km south of the border with Belarus, consisted of four nuclear reactors of the RBMK-1000 design, units 1 and 2 being constructed between 1970 and 1977, while units 3 and 4 of the same design were completed in 1983. Two more RBMK reactors were under construction at the site at the time of the accident. To the southeast of the plant, an artificial lake of some 22 square kilometres, situated beside the river Pripyat, a tributary of the Dniepr, was constructed to provide cooling water for the reactors.

This area of Ukraine is described as Belarussian-type woodland with a low population density. About 3 km away from the reactor, in the new city, Pripyat, there were 49,000 inhabitants. The old town of Chornobyl, which had a population of 12,500, is about 15 km to the southeast of the complex. Within a 30 km radius of the power plant, the total population was between 115,000 and 135,000.

On 25 April, prior to a routine shutdown, the reactor crew at Chernobyl 4 began preparing for a test to determine how long turbines would spin and supply power to the main circulating pumps following a loss of main electrical power supply. This test had been carried out at Chernobyl the previous year, but the power from the turbine ran down too rapidly, so new voltage regulator designs were to be tested.

A series of operator actions, including the disabling of automatic shutdown mechanisms, preceded the attempted test early on 26 April. By the time that the operator moved to shut down the reactor, the reactor was in an extremely unstable condition. A peculiarity of the design of the control rods caused a dramatic power surge as they were inserted into the reactor.

The overpressure caused the 1000 t cover plate of the reactor to become partially detached, rupturing the fuel channels and jamming all the control rods, which by that time were only halfway down. Intense steam generation then spread throughout the whole core (fed by water dumped into the core due to the rupture of the emergency cooling circuit) causing a steam explosion and releasing fission products to the atmosphere. About two to three seconds later, a second explosion threw out fragments from the fuel channels and hot graphite. There is some dispute among experts about the character of this second explosion, but it is likely to have been caused by the production of hydrogen from zirconium-steam reactions.